4, Acute Tox. References. REACH regulation aims to improve the protection of human health and the environment from the risks that can be posed by chemicals. COVID-19 is an emerging, rapidly evolving situation. Burning lithium manganese dioxide batteries produce toxic and corrosive lithium hydroxide fumes. In the event offire, wear full protective clothing and NIOSH-approved self-containedbreathing apparatus with full face piece operated in the pressure demand orother positive pressure mode. For use on containers that store Manganese Dioxide to ensure the workplace is aware of the immediate chemical hazards that are present. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and indoor use in long-life materials with low release rate (e.g. Extinguishing Media: Use dry chemical, alcohol foam, water or carbon dioxide as appropriate for the surrounding fire. Release to the environment of this substance can occur from industrial use: in the production of articles. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). The date of the last update corresponds to the publication date of the InfoCard and not necessarily to the date in which the update occurred in the source data. 2. PREVENT … Other release to the environment of this substance is likely to occur from: indoor use in long-life materials with low release rate (e.g. Manganese can also cause Parkinson, lung embolism and bronchitis. Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance causes damage to organs through prolonged or repeated exposure. This substance can be found in products with material based on: stone, plaster, cement, glass or ceramic (e.g. It is possible that a harmonisation is introduced through an amendment to the CLP Regulation. Manganese dioxide (CAS-No. Manganese dioxide can slightly stain human skin if it is damp or in a heterogeneous mixture, but the stains can be washed off quite easily with some rubbing. This substance is used in the following products: adhesives and sealants, adsorbents, coating products, fuels and oil and gas exploration or production products. The classifications of the substances listed in the list are based on their harmonised classifications per Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. ECHA organises consultations to get feedback from all interested parties and to gather the widest possible range of scientific information for the regulatory processes. Carcinogenicity: <> Manganese effects occur mainly in the respiratory tract and in the brains. plasters, cement) and rubber products. Manganese(II) oxide | MnO | CID 14940 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. Manganese dioxide can slightly stain human skin if it is damp or in a heterogeneous mixture, but the stains can be washed off quite easily with some rubbing. endobj Manganism’s symptoms, similar to … Other release to the environment of this substance is likely to occur from: indoor use in long-life materials with low release rate (e.g. In case of fire in the surroundings, use appropriate extinguishing media. 1313-13-9 Revision Date 1987-01-01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components No components are subject to the Massachusetts Right to Know Act. In the past manufacturers used pure manganese dioxide as a body addition to create a black fired surface. It covers their hazardous properties, classification and labelling, and information on how to use them safely. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. Early symptoms include languor, sleepiness and weakness in the legs. This substance has an industrial use resulting in manufacture of another substance (use of intermediates). This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). /PageMode /UseNone 3 0 obj 1313-13-9 Revision Date 1987-01-01 Welcome to PubChem! 2 0 obj Hazardous Substances - Article 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. )]: May react violently or explosively on contact with water. InfoCards are generated automatically based on the data available at the time of generation. Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance causes damage to organs through prolonged or repeated exposure. f Inhaling Manganese can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. Substances for which classification and labelling data have been notified to ECHA by manufacturers or importers. <> : AC317440000; AC317440010; AC317442500 CAS-No 7439-96-5 Synonyms No information available Recommended Use Laboratory chemicals. According to the annexes to Directive 92/58/EEC, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation must be duly marked and/or labeled. The CAS number is the substance numerical identifier assigned by the Chemical Abstracts Service, a division of the American Chemical Society, to substances registered in the CAS registry database. Other release to the environment of this substance is likely to occur from: outdoor use, indoor use (e.g. 6(5) - SDS and Declaration, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, End-of-Life Vehicles Directive - Hazardous Substances, Active Implantable Medical Devices Directive - Hazardous Substances, In Vitro Diagnostic Medical Devices Directive - Hazardous Substances, Marine Environmental Policy Framework Directive - Hazardous Substances, Medical Devices Directive - Hazardous Substances, General Product Safety Directive - Hazardous Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Safety and Health of Workers at Work Directive - Hazardous Substances, Waste Framework Directive, Annex III - Waste - Hazardous Properties, C&L Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. Such notifications are required for hazardous substances, mixtures, or articles, manufactured or imported at over 1 kg per annum. If the substance is covered by more than one CLH entry (e.g. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. what is ?) For readability purpose, only non-confidential use descriptors occurring in more than 5% of total occurrences are displayed. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment) and outdoor use in long-life materials with low release rate (e.g. Chronic manganese poisoning primarily involves the central nervous system. External links . Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. 2, Acute Tox. Hazards Safety data sheet: ICSC 0175: EU classification (DSD) (outdated) Harmful (Xn) Oxidizer (O) R-phrases (outdated) R20/22: S-phrases (outdated) (S2), S25: NFPA 704 (fire diamond) 1. While the harmonised list covers many hazardous substances, others not listed may also meet classification criteria in accordance with the CLP Regulation. PubChem Substance ID 24852197 Manganese (Mn) is a hard, gray metal that is frequently used in the production of steel. The EU Ecolabel may not be awarded to substances or mixtures classified as such. Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. Hazards EU classification: Harmful (Xn) Oxidizer (O) NFPA 704 : 1. disodium tetraborate EC no. Manganese (Mn) is a hard, gray metal that is frequently used in the production of steel. First Aid Measures 4.1. Molecular Weight 86.94 . H335 May cause respiratory irritation. This is unique source of information on the chemicals manufactured and imported in Europe. It is a dangerous oxidizer and was first described in 1860. Details of dossier compliance checks and testing proposal evaluation. This practice obviously puts workers at risk to the toxic effects of the dust. Cylindrical Lithium Manganese Dioxide Cells and Batteries (Perchlorate Style) Manufacturer Name/Address Ultralife Corporation 2000 Technology Parkway Newark, NY 14513 24 Hour Emergency Contact ChemTrec 800-424-9300 (US) 703-527-3887 (International) Technical Contact 800-332-5000 Issue Date 02 MAY 01 Prepared By Dave Gould Revision Date: 15 DEC 20 Section 2 - HAZARDS … If at least one company has indicated that the substance classification is affected by impurities or additives, this will be indicated by an informative sentence. If available, additional information on classification and labelling (C&L) is derived from REACH registration dossiers submitted by industry. Manganese(IV) oxide (Manganese dioxide) a fine powder. Manganese dioxide (CAS-No. Manganese disulfide: Other cations. Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. Substances according to Hazardous Waste Properties: Annex III, Directive 2008/98/EC, 22 November 2008, amended by Directive 2018/851/EU, 14 June 2018, Registration, Evaluation, Authorisation and Restriction of Chemicals, Chemical Agents Directive and Carcinogens or Mutagens Directive, Safety and/or Health Signs at Work Directive, EC Inventory, Pre-Registration process, CAD - Chemical Agents Directive, Art. The EC Number is the numerical identifier for substances in the EC Inventory. Details of the supplier … 1 Skin Corr. SECTION 6 - ACCIDENTAL RELEASE MEASURES To cleanup leaking batteries: Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries. Substances which have been registered and can be placed on the EEA market by those companies with a valid registration. Manganese(II) sulfate. Slags coming from old converters, as in the Thomas process in the steel industry, can be used as fertilizers. 6(5) - SDS and Declaration, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, End-of-Life Vehicles Directive - Hazardous Substances, Active Implantable Medical Devices Directive - Hazardous Substances, In Vitro Diagnostic Medical Devices Directive - Hazardous Substances, Marine Environmental Policy Framework Directive - Hazardous Substances, Medical Devices Directive - Hazardous Substances, General Product Safety Directive - Hazardous Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Safety and Health of Workers at Work Directive - Hazardous Substances, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Other, Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). Directive 92/58/EEC requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. Toxic to aquatic life with long-lasting effects. Molecular Weight 86.94 . Hazard statement(s) H319 Causes serious eye irritation. Theoretically, alkaline-manganese dioxide cells have a higher capacity than Leclanche, or zinc-carbon cells, of similar sizes. <> Iron(II) oxide: Related manganese oxides. Substances may have impurities and additives that lead to different classifications. OX. Chemicals and Solutions Hydrogen Peroxide, 30% Manganese Dioxide, solid Materials cylinder spatula Procedure Pour some hydrogen peroxide into the cylinder and add a small spatula scoop of MnO₂. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). 2 H319 1,2 dimethoxy ethane (DME)** 110-71-4 1 - 3.5 Flam Liq. Some are transported in flammable liquids. The EC or list number is the primary substance identifier used by ECHA. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment). A substance may have its use restricted to certain articles or products and therefore not all the examples may apply to the specific substance. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. metal, wooden and plastic construction and building materials). If the substance was not covered by the EC Inventory, ECHA attributes a list number in the same format, starting with the numbers 6, 7, 8 or 9. 4 0 obj This substance is used in the following products: pH regulators and water treatment products, metals and polymers. Manganese compounds used by potters are inorganic , like manganese dioxide, oxide and manganese carbonate. Advanced cases have shown fixed facial expression, emotional disturbances, spastic gait, and falling. 1313-13-9 Revision Date 1987-01-01 Solid and concentrated solutions (if 0.7 M or more) HEALTH ENVIRONMENT . Empirical Formula (Hill Notation) MnO 2. 2 R-phrases: R20/22: S-phrases (S2), S25: Related compounds Other anions: Manganese disulfide: Other cations: Technetium dioxide Rhenium dioxide: Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Substances Rendering Goods Ineligible for EU Ecolabel, Article 6(6), Regulation 66/2010/EC, L 27/1, 30 January 2010 (Table 3 of Annex VI to CLP; Candidate List of SVHCs), EU. This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. But it also put potters and manufacturers at risk to the fumes produced during firing. In the event offire, wear full protective clothing and NIOSH-approved self-containedbreathing apparatus with full face piece operated in the pressure demand orother positive pressure mode. Section VI: Health Hazard Data Route of Entry: MANGANESE DIOXIDE.doc Laguna Clay Company Page 1of2 Not combustible LEL NA Foam, CO2, dry chemical or water. 2(b)(i) - Hazardous Agents, Construction Product Regulation - Annex I (3) - Hazardous Substances, Construction Product Regulation - Art. Note that this list is not exhaustive. Hazard statement(s) H319 Causes serious eye irritation. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. Note that for readability purposes, only the pictograms, signal words and hazard statements referred in more than 5% of the notifications under CLP are displayed. Occupational exposure limit (OEL) values are derived within two legal frameworks that form an integral part of the EU’s mechanism for protecting the health of workers. Manganese dioxide CAS Number: 1313-13-9 EC Number: 215-202-6 The hazard endpoint for which vertebrate testing was proposed: ... scientifically valid information and studies that address the relevant substance and the hazard endpoint mentioned above for which testing is proposed. Tool showing an overview of substances in various key regulatory processes that authorities are working on. Manganese is a pinkinsh-gray, chemically active element. Release to the environment of this substance can occur from industrial use: manufacturing of the substance and as an intermediate step in further manufacturing of another substance (use of intermediates).
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